PREVIOUS ARTICLE
NEXT ARTICLE

Synthesis of novel nitroso acetal derivatives via tandem 6π-electrocyclization/ [3+2]-cycloaddition of 1-nitro-2-methyl-1,3 butadiene

Original Article

JOURNAL 827

Organic Communications
VOLUME & ISSUE
Year: 2017 Issue: 4 October-December
PAGES
p.298 - 303
DOI ADDRESS
http://doi.org/10.25135/acg.oc.30.17.08.045
STATISTICS
Viewed 2329 times.
AUTHORS
    Esra Koc
PDF OF ARTICLE

GRAPHICAL ABSTRACT

ABSTRACT

Novel nitroso acetal derivatives (4-methyl-2,3,3a,6-tetrahydroisoxazolo[2,3-b][1,2]oxazine) were synthesized through 6π-electrocyclization/[3+2]-cycloaddition reaction of several dionophiles with 1-nitro-2-methyl-1,3-butadiene. Structures of the synthesized compounds were determined by 1H-NMR, 13C-NMR, IR and GC-MS analyses.

 KEYWORDS
  • Nitrodiene
  • nitroso acetal
  • 6π-electrocyclization
  • [3 + 2] cycloaddition
  • pericyclic reactions