Organic Communications

Year: 2009 Volume: 2 Issue:4 October-December

Review Article

1) Utility of cyclohexanethiols in organic synthesis

Org. Commun. (2009) 2:4 ; 84 - 119
by Mohamed A. Metwally and Bakr F. Abdel-Wahab

Publications on the preparations of cyclohexanethiols and its reactions are reviewed for the first time.

Keywords
Cyclohexanethiols disulphides displacement reactions
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© 2009 ACG Publications. All rights reserved.
Original Article

2) Synthesis, spectral and antimicrobial activity of [3-(4-chloro-phenoxy)-2,4-diisopropyl)-2,3,4,5-tetrahydro-1H-3l5-benzo[e][1,3,2]diazaphosphepin-3-ylidene]-alkyl-amine (Staudinger reaction)

Org. Commun. (2009) 2:4 ; 120 - 127
by Ch. Mohan, A. Janardhan Rao, C. Naga Raju and R. Usha Nagalakshmi

3-(4-chlorophenoxy)-2,4-diisopropyl-2,3,4,5-tetrahydro-1H-benzo[e][1,3,2]diaza-phosphepine was synthesized starting from  1,2-bis(bromomethyl)benzene by reacting with  2 equimolar isopropyl amine, one equimolar PBr3 and then one equimolar 4-chlorophenol, respectively. The Staudinger reaction of the diazaphphosphine with a series of  alkyl azides gave the corresponding iminophosphoranes. Antibacterial activities of the synthesized iminophosphoranes  were screened

Keywords
Iminophosphoranes 1 2-bis(bromomethyl)benzene Isopropylamine phosphorus tribromide 4-chlorophenol alkyl azides
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© 2009 ACG Publications. All rights reserved.